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・ Phosphorus nitride
・ Phosphorus oxide
・ Phosphorus pentabromide
・ Phosphorus pentachloride
・ Phosphorus pentafluoride
・ Phosphorus pentaiodide
・ Phosphorus pentasulfide
・ Phosphorus pentoxide
・ Phosphorus selenide
・ Phosphorus sesquisulfide
・ Phosphorus sulfide
・ Phosphorus tribromide
・ Phosphorus tribromide (data page)
・ Phosphorus trichloride
・ Phosphorus trichloride (data page)
Phosphorus trifluoride
・ Phosphorus trifluoride (data page)
・ Phosphorus triiodide
・ Phosphorus triiodide (data page)
・ Phosphorus trioxide
・ Phosphorus trisulfide
・ Phosphorus-31 nuclear magnetic resonance
・ Phosphorus-32
・ Phosphoryl bromide
・ Phosphoryl chloride
・ Phosphoryl chloride (data page)
・ Phosphoryl fluoride
・ Phosphoryl group
・ Phosphoryl nitride
・ Phosphorylase


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Phosphorus trifluoride : ウィキペディア英語版
Phosphorus trifluoride

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Phosphorus trifluoride (formula PF3), is a colorless and odorless gas. It is highly toxic and reacts slowly with water. Its main use is as a ligand in metal complexes. As a ligand, it parallels carbon monoxide in metal carbonyls, and indeed its toxicity is due to its binding with the iron in blood hemoglobin in a similar way to carbon monoxide.
==Physical properties==
Phosphorus trifluoride has a bond angle of 107°, F-P-F bond angle being 96.3°. Gaseous PF3 has a standard enthalpy of formation of -945 kJ/mol (-226 kcal/mol). The phosphorus atom has a nuclear magnetic resonance chemical shift of 97 ppm (downfield of H3PO4).

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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